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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Asymmetric ion-pairing catalysis ： ウィキペディア英語版 Asymmetric ion-pairing catalysis Asymmetric ion-pairing catalysis in chemistry is a type of asymmetric catalysis taking place specifically with charged intermediates or charged reagents. In one type of catalysis ion-pairing exists with a charged and chiral catalyst. The charged catalyst can be cationic or anionic. Catalysis by anionic catalysts is also called asymmetric counteranion-directed catalysis. In the other variation of asymmetric ion-pairing catalysis called anion or cation binding, the chiral catalyst is neutral but binds in a noncovalent way to an intermediate ion pair. Asymmetric ion-pairing catalysis is distinct from other covalent types of catalys such as Lewis acid catalysis and Brønsted acid catalysis.〔Brak, K. and Jacobsen, E. N. (2013), Asymmetric Ion-Pairing Catalysis. Angew. Chem. Int. Ed., 52: 534–561. 〕 It is one of several strategies in enantioselective synthesis and of some relevance to academic research. The first reported example of this type of catalysis is attributed to Dolling, Davis & Grabowski who in 1984 used a chiral cinchonidine based phase transfer catalyst in the synthesis of indacrinone.〔''Efficient catalytic asymmetric alkylations. 1. Enantioselective synthesis of (+)-indacrinone via chiral phase-transfer catalysis'' Ulf H. Dolling, Paul Davis, and Edward J. J. Grabowski Journal of the American Chemical Society 1984 106 (2), 446-447 〕 Important chiral cation scaffolds are quaternary ammonium cations and quaternary phosphonium cations. The first reported example of asymmetric cation-binding catalysis originates from Cram and Sogah who in 1981 used a chiral crown ether in combination with a potassium base in an enantioselective Michael addition.〔''Chiral crown complexes catalyse Michael addition reactions to give adducts in high optical yields'' Donald J. Cram and G. D. Y. Sogah J. Chem. Soc., Chem. Commun., 1981, 625-628 〕 The development of chiral anionic catalysists is a more recent research field. In 2000 Llewellyn, Adamson & Arndtsen used a chiral borate anion in olefin aziridination and cyclopropanation.〔''A Novel Example of Chiral Counteranion Induced Enantioselective Metal Catalysis:  The Importance of Ion-Pairing in Copper-Catalyzed Olefin Aziridination and Cyclopropanation'' David B. Llewellyn,Dan Adamson, and, and Bruce A. Arndtsen Organic Letters 2000 2 (26), 4165-4168 〕 Another regularly encountered scaffold is a chiral phosphate anion together with iminium, carbocationic or oxocarbenium counterions. Chiral anion phase-transfer catalysis was introduced by Toste in 2007 〔''Chiral Anion-Mediated Asymmetric Ring Opening of meso-Aziridinium and Episulfonium Ions'' Gregory L. Hamilton, Toshio Kanai, and F. Dean Toste Journal of the American Chemical Society 2008 130 (45), 14984-14986 〕 ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Asymmetric ion-pairing catalysis」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.